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Particle Tracking Microrheology of Complex Fluids

by: TG Mason, K Ganesan, JH van Zanten, D Wirtz, SC Kuo
Physical Review Letters, Vol. 79, No. 17. (27 October 1997), 3282.


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We present a new method for measuring the linear viscoelastic shear moduli of complex fluids. Using photodiode detection of laser light scattered from a thermally excited colloidal probe sphere; we track its trajectory and extract the moduli using a frequency-dependent Stokes-Einstein equation. Spectra obtained for polyethylene oxide in water are in excellent agreement with those found mechanically and using diffusing wave spectroscopy. Since only minute sample volumes are required; this method is well suited for biomaterials of high purity; as we demonstrate with a concentrated DNA solution.


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