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NMR Observation of Rattling Phonons in the Pyrochlore Superconductor KOs_2O_6

by: M Yoshida, K Arai, R Kaido, M Takigawa, S Yonezawa, Y Muraoka, Z Hiroi
Physical Review Letters, Vol. 98, No. 19. (May 2007), 197002.


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We report nuclear magnetic resonance studies on the beta-pyrochlore oxide superconductor KOs<SUB>2</SUB>O<SUB>6</SUB>. The nuclear relaxation at the K sites is entirely caused by fluctuations of the electric field gradient, which we ascribe to highly anharmonic low frequency oscillation (rattling) of K ions. A phenomenological analysis shows a crossover from overdamped to underdamped behavior of the rattling phonons with decreasing temperature and its sudden sharpening below the superconducting transition temperature T<SUB>c</SUB>. Suppression of the Hebel-Slichter peak in the relaxation rate at the O sites below T<SUB>c</SUB> also indicates strong electron-phonon coupling.


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