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Uncommonly high upper critical field of the pyrochlore superconductor KOs_2O_6 below the enhanced paramagnetic limit

Physical Review B (Condensed Matter and Materials Physics), Vol. 74, No. 22. (December 2006), 220506.


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The entire temperature dependence of the upper critical field H<SUB>c2</SUB> in the beta -pyrochlore KOs<SUB>2</SUB>O<SUB>6</SUB> is obtained from high-field resistivity and magnetic measurements. Both techniques identically give H<SUB>c2</SUB>(T~=0K) not only surprisingly high (˜33T) , but also the approach to it is unusually temperature linear all the way below T<SUB>c</SUB>(=9.6K) . We show that, while H<SUB>c2</SUB>(0) exceeds a simple spin-singlet paramagnetic limit H<SUB>P</SUB> , it is well below an H<SUB>P</SUB> enhanced due to the missing spatial inversion symmetry reported recently in KOs<SUB>2</SUB>O<SUB>6</SUB> , ensuring that the pair breaking here is executed by orbital degrees. Ab initio calculations of orbital H<SUB>c2</SUB> show that an unusual temperature dependence is reproduced if dominant s -wave superconductivity resides on the smaller closed Fermi surfaces.


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