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Scattering experiments for the microscopic understanding of the glass transition

by: E Bartsch
Journal of Non-Crystalline Solids, Vol. 192-193 (2 December 1995), pp. 384-392.


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Scattering experiments studying the dynamics of glass-forming systems have become of special importance for understanding glass transition phenomena. They monitor the density autocorrelation function which has become a key observable since it is calculated within a new concept of the glass transition, the mode coupling theory (MCT). After a short reference to the main predictions and examples of scattering experiments where these phenomena have been observed, results for two model systems will be analyzed with MCT: a recently reported analysis of neutron scattering data for orthoterphenyl in the [beta]-regime is improved and photon correlation spectroscopy data on colloidal spheres are described by simultaneously analyzing the [beta]- and [alpha]-relaxation dynamics using the MCT scaling laws.


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