Fluorescence correlation spectroscopy as a probe of molecular dynamics

@article{citeulike:1082835, abstract = {A general theory of fluorescence correlation spectroscopy (FCS), including the effects of translational and rotational motions and chemical reactions, in ideal solutions, is given. The development is carried out explicitly for symmetric rotors of parallel transition moments and generalized to arbitrary configurations of the moments and to asymmetric rotors in the appendices. In addition, the effects of experimental geometry on the measured FCS correlation function are discussed in detail and the optimum geometries, for experiments seeking to measure different quantities, are given. We conclude with a brief discussion of signal-to-noise ratios and prospects for applications. The Journal of Chemical Physics is copyrighted by The American Institute of Physics. doi:10.1063/1.432357 PACS: 32.20.Jx \ \ \ \ \ \  Additional Information Full Text: \ [\  PDF (1006 kB) }, author = {Aragon, S. R. and Pecora, R. }, citeulike-article-id = {1082835}, comment = {Some theory about fluorescence correlation at mere diffusion.}, doi = {10.1063/1.432357}, journal = {The Journal of Chemical Physics}, keywords = {diffusion, fcs, theory}, number = {4}, pages = {1791--1803}, posted-at = {2007-02-02 02:47:53}, priority = {0}, publisher = {AIP}, title = {Fluorescence correlation spectroscopy as a probe of molecular dynamics}, url = {http://scitation.aip.org/getabs/servlet/GetabsServlet?prog=normal\&id=JCPSA6000064000004001791000001\&idtype=cvips\&gifs=yes}, volume = {64}, year = {1976} }

TY - JOUR ID - citeulike:1082835 L3 - citeulike-article-id:1082835 TI - Fluorescence correlation spectroscopy as a probe of molecular dynamics JF - The Journal of Chemical Physics VL - 64 IS - 4 SP - 1791 EP - 1803 PB - AIP N2 - A general theory of fluorescence correlation spectroscopy (FCS), including the effects of translational and rotational motions and chemical reactions, in ideal solutions, is given. The development is carried out explicitly for symmetric rotors of parallel transition moments and generalized to arbitrary configurations of the moments and to asymmetric rotors in the appendices. In addition, the effects of experimental geometry on the measured FCS correlation function are discussed in detail and the optimum geometries, for experiments seeking to measure different quantities, are given. We conclude with a brief discussion of signal-to-noise ratios and prospects for applications. The Journal of Chemical Physics is copyrighted by The American Institute of Physics. doi:10.1063/1.432357 PACS: 32.20.Jx        Additional Information Full Text:  [  PDF (1006 kB) KW - diffusion KW - fcs KW - theory N1 - Some theory about fluorescence correlation at mere diffusion. AU - Aragon, SR AU - Pecora, R PY - 1976/// UR - http://scitation.aip.org/getabs/servlet/GetabsServlet?prog=normal&id=JCPSA6000064000004001791000001&idtype=cvips&gifs=yes ER -