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Spontaneous Assembly of Perfectly Ordered Identical-Size Nanocluster Arrays

by: Jian-Long Li, Jin-Feng Jia, Xue-Jin Liang, Xi Liu, Jun-Zhong Wang, Qi-Kun Xue, Zhi-Qiang Li, John S Tse, Zhenyu Zhang, SB Zhang
Physical Review Letters, Vol. 88, No. 6. (25 January 2002), 066101.


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A method; by which periodic two-dimensional arrays of identical metal clusters of nanometer size and spacing could be spontaneously obtained by taking advantage of surface mediated clustering; is reported. The versatility of the method is demonstrated for a broad range of metals on Si(111)-(7Ã7) substrates. In situ scanning tunneling microscopy analysis of In clusters; combined with first-principles total energy calculations; unveils unique initial-stage atomic structures of the surface-supported clusters and the vital steps that lead to the success of this method. A strong interaction between the clusters and the surface holds the key to the observed cluster sizes.


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